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Last Time, in Steel History….
When we last left steel history, the first high speed steels had been developed which had led to an explosion in steel development. I covered all of this in The History of the First Tool Steel. A few highlights of that article:
Update: I have started a Patreon page to fund research projects which you can read about here – http://knifesteelnerds.com/how-you-can-help/
To harden steel you heat it up to high temperature to form a phase called austenite, followed by rapid quenching to make a very strong phase called martensite. Hardness is a measure of strength. I covered the process of austenite formation in the following post: Austenitizing Part 1. To summarize that post:
This past week I did a quiz on my site to get a feel for the level of knowledge of my readership (or at least the ones that take quizzes) and of course for fun: Take the Quiz Here.
At the time of writing there are more than 900 responses to the quiz (update: 1000!), which I think is a success. I have performed some analysis of the results of the quiz and so I will go over some of the questions that tripped people up and how I might adjust what I write about on this site based on the responses.
High carbon, tungsten-alloyed forging steels see consistent use in Japanese knives with steels like the Hitachi Blue series and Takefu V-Toku steels. These steels differentiate themselves from many other knife steels due to their use of tungsten alloying, but not for providing hot hardness like in high speed steels, but for wear resistance. Tungsten-alloyed steels are as old as tool steels themselves, as I covered in an earlier post: The First Tool Steel. However, simple tungsten-alloyed steels have been on their way out in the USA since at least the early 60’s [1]. The tungsten added to the steels leads to the formation of very hard tungsten carbides for steels that can be as wear resistant as air hardening steels like D2 or M2 but with the ability to normalize and anneal the steels without precise temperature control.
Cru Forge V was developed by Crucible for those who forge their steel for knives [1]. It was developed shortly before Crucible’s bankruptcy and is reported to have been tested with the help of knifemakers Howard Clark and Dan Farr and that the code name prior to its official name was 1086V [2]. The steel is not listed anywhere on Crucible’s website and does not appear to be in production any longer, but as of March 2018 is still available from some third party steel sellers [3][4][5]. The steel has the following composition [1]:
The steel largely recognized as being the “first tool steel” was developed by Robert Forester Mushet, a British metallurgist, in 1868 [1]. Mushet improved the Bessemer steelmaking process through the addition of a small amount of manganese [1]. Later Mushet was experimenting with various additions of elements and discovered that one of his bars of steel had become fully hard despite not being quenched. This was called a “self-hardening” and later “air-hardening” steel because it could be fully hardened in air rather than requiring a water or even oil quench. The reason for the ability to self-harden is due to the property of hardenability, which I have covered in a Bladeforums post [2]. Hardenability is essentially the property of how slowly a steel can be cooled from the hardening temperature while still achieving a hard martensitic microstructure rather than a soft ferrite-cementite microstructure. This steel was high in tungsten and manganese, and it is sometimes erroneously reported that it was the tungsten that gave it the high hardenability; however, it was primarily the manganese that gave it the ability to harden in air, as tungsten adds little to hardenability [3].
Update 6/21/2018: A new journal article has been released on the effect of grain size which is very interesting. I have added a brief summary of it at the bottom of this article.
In my posts on austenitizing I described parameters of heat treating to keep grain size as small as possible and therefore improve strength and toughness [1-3]. It is very difficult to improve both strength and toughness at the same time, usually increasing one decreases the other. By what mechanism does grain refinement improve both?
Update: 1/6/2020: I have taken micrographs of many more steels which you can see here.
Recently I had samples of Niolox, CPM-154, and AEB-L analyzed with SEM. Vilella’s reagant was used which is common for tool steels and martensitic stainless steels because it etches the martensite matrix so it is dark and leaves the carbides bright. The compositions for the three steels:
One concept that can be difficult to understand intuitively is that the hardness or strength of steel does not change its stiffness. Meaning, “flexing” steel without permanently bending it is not changed by its hardness. I have heard many people swear up and down that they can tell a difference, so I found a great Youtube video that illustrates this [1]:
