Update 10/29/2020: Since writing this article I published my own book called Knife Engineering: Steel, Heat Treating, and Geometry. Of course I still recommend the other books on the list below.
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Update 7/23/2018: I added a small piece of new information on the development of 440C steel to the article.
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The writing of this article was made much easier due to the existence of The History of Stainless Steel by Harold Cobb [1]. If you want more information on the history of stainless and the people who developed it, check out the book.
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Misc. update: I have added a set of supporting micrographs to the introduction to Austenitizing steel.
Tempered Martensite
To begin describing what bainite is it makes sense to start with martensite first. To form martensite we heat up the steel to high temperature to transform to a phase called austenite where we dissolve carbon in between the iron atoms (see Austenitizing Part 1), then quench the steel to lock in the carbon and form a hard phase called martensite (see What Makes Quenched Steel so Hard?). Following that we temper the martensite to allow some of the carbon out and increase the ductility of the martensite; the carbon comes out as very small carbides, a compound of iron and carbon (see What Happens During Tempering?). In the article on martensite formation I shared the following YouTube video to see the formation of the martensite laths:
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Misc. updates: I added some toughness numbers that I had previously been unable to track down comparing 440C and 154CM to the 154CM article. I also added a summary of a very interesting new journal article about the effect of grain size on steel toughness to the Grain Refinement article.
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CATRA
Update 1/6/2020: I have since written more articles about CATRA looking at the effect of steel type: Part 1 and Part 2
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Some materials like aluminum form a passive oxide layer that prevents further corrosion. Steel is not one of those materials. Instead, steel forms iron oxide, or rust, that doesn’t protect the underlying iron and flakes off leading to further corrosion. However, when sufficient chromium is added then a chromium oxide passive layer forms which protects the steel from corrosion in a similar way to a metal like aluminum with its own aluminum oxide layer. A simple schematic diagram shows the passive film vs rust [1]:
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I recently completed some toughness tests on samples that were heat treated by knifemaker Warren Krywko. The steel was donated by Chuck Bybee of Alpha Knife Supply. The samples are subsize unnotched charpy specimens with dimensions as specified on the bottom of this page: http://knifesteelnerds.com/how-you-can-help/ If we can get more people to make toughness specimens we can have more comparisons between steels, hardness points, heat treatment parameters, etc. Patreon dollars are for the purpose of paying for machining, shipping, testing, etc. for tests like toughness and CATRA edge retention, so if you are able to contribute that way please visit the Knife Steel Nerds Patreon page.
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To discuss chipping we have to start with fracture mechanics of materials, and in this case steel. Chipping itself is just fracture, so by definition resistance to chipping is controlled by toughness. Unfortunately there are many definitions of toughness. I covered one definition of toughness in the article on spider silk, which is the area underneath the stress-strain curve:
Update 6/19/18: I have added new toughness numbers from a 1962 publication comparing 440C and 154CM. Go to the bottom of the article to see them. Thanks to Russ Andrews for sending me the article.
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