Category: Heat Treating and Processing
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A2 Steel – History and Properties
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History
A2 steel is quite old, though determining the exact year it was released is a bit difficult. A2 steel was developed in the early 20th century during the explosion of tool steels that occurred after the discovery of high speed steel which was first presented in 1900. You can read about that history in this article: The History of the First Tool Steel. During the development of the first high speed steel included the switch from manganese to chromium as the primary hardenability element, and most high speed steels had about 4% Cr. That high chromium content was primarily for “hardenability” which is the degree of cooling required to achieve full hardness. A “water quenching” steel has low hardenability and must be quenched very rapidly from high temperature, and an “air hardening” steel can be left in air and it will fully harden. You can read more about hardenability in this article on quenching. The first high speed steel came to be known as T1, which had 4% Cr and 18% W (tungsten). The earliest record I have found of a precursor A2-type steel is in a summary of tool steels in 1925 [1], while summaries of tool steels from 1910 [2] and 1915 [3] do not have any similar steels. Therefore these types of steels probably arose sometime between 1915 and 1925.
How to Heat Treat 5160 – Optimizing Toughness
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5160
5160 is a low alloy steel known for its excellent toughness. It has been used by many forging bladesmiths due to its good properties and also wide availability, especially in the form of leaf springs. However, information on how to maximize the steel’s properties with heat treating is scant. So along with my father, Devin Thomas, we did a small study on the toughness of 5160.
Heat Treating Vanax – How Hard Does it Get?
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Vanax
Vanax is an interesting steel because of its good combination of toughness, wear resistance, and corrosion resistance. I wrote about Vanax along with other nitrogen-alloyed steels in this article, to describe how the steel is designed. While the datasheet shows it being capable of 59-61 Rc, I was curious about how hard the steel can go. The steel may be good for kitchen knives, for example, where very thin edges and high hardness is common. And kitchen knife users may appreciate the excellent corrosion resistance of Vanax in the presence of water, salt, and acidic foods.
Can You Trust Your Magnet During Heat Treating?
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How a Magnet Helps in Heat Treating
It is somewhat common for knifemakers to heat treat low alloy steels in a forge or with a torch, two methods where tight temperature control is not possible, and the temperature is frequently not even known. A magnet is often used to check the temperature of the steel because the point at which the steel becomes nonmagnetic is near the temperature at which the steel should be quenched to achieve high hardness. How does steel magnetism work? How reliable is checking the steel with a magnet?
Cold Forging of Steel
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Cold Forging
Cold forging is a lot like hot forging except it is at or near room temperature. The lower temperature means that the steel is much stronger and it is much more difficult to forge. That also means the steel is more brittle and therefore more likely to crack during forging or rolling. The shape of the grains in the steel are changed through forging. You can read about what grains are in this article. Steel is made up of planes of iron atoms, and if the steel was made up of only one grain these planes of atoms would all be parallel to each other:
How Fast Do You Have to Quench? Hardenability of Steel
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Hardenability
How fast one must quench steel is controlled by its hardenability. Hardenability is not a measure of how hard a steel can get. Instead it is a measure of how fast you have to quench to achieve max hardness for a given composition. Therefore a steel with 0.2% carbon can have high hardenability without being able to reach a particularly high hardness; the steel can be allowed to cool in air and achieve more or less the same hardness as when it is quenched in water. On the other hand, a steel with very high carbon content that can reach very high hardness can have low hardenability, requiring a water quench to achieve its potential hardness.
Cryogenic Processing of Steel Part 3 – Wear Resistance and Edge Retention
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Intro to Cryo and Wear Resistance
In Cryogenic Processing Part 1 I covered the effects of cryo on retained austenite and hardness. In Cryogenic Processing Part 2 I looked at the studies on cryo and toughness. Wear resistance is the most controversial aspect of cryogenic processing of steel. In particular there are claims that the use of cryogenic processing (liquid nitrogen) leads to an improvement in wear resistance that is not found with subzero processing (dry ice). Sometimes it is claimed that cryo can lead to massive increases in wear resistance [1]:
Cryogenic Processing of Steel Part 2 – Toughness and Strength
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Introduction
Part 1 of the Cryogenic Processing series covered the transformation of retained austenite to martensite and the increase in hardness that occurs. That is the least controversial aspect of cryogenic processing of steel. The other two primary properties of steel affected by cryo processing are toughness and wear resistance. Both of these properties can be difficult to pin down as they have high variability. Tool steels are known for their relatively poor toughness which means we are often comparing small numbers.
Detour – Tempering
One important interrelation to keep in mind with subzero and cryo studies is the transformation of retained austenite in tempering. With sufficiently high tempering temperatures all/most of the retained austenite is transformed without any cold treatment. This depends on the alloy content, as low-alloy 52100 will have lost its retained austenite with a 500-600°F temper while high alloy steels need over 900°F. You can read more in the article on tempering. With high alloy steels the loss of retained austenite also coincides with “secondary hardening” which is a high temperature tempering treatment that increases hardness [1]:
Above is a tempering chart for Caldie steel (0.7C-5.0Cr-2.3Mo) which shows both hardness vs hardening temperature and also retained austenite. You can see that at low tempering temperatures (<400°C) the retained austenite is basically constant. You can also see that the hardness decreases with higher tempering temperatures up to about 350°C and then it increases to a peak at around 520°C (950°F). Therefore tempering in the secondary hardening region above 400°C can lead to both high hardness and also the elimination of retained austenite.
Subzero or cryo processing prior to tempering also shifts the tempering-hardness curve to lower temperatures when using the secondary hardening range of tempering [2]:
This means that in general, a lower tempering temperature is required to achieve the same hardness level with secondary hardening. Using the same tempering temperature as without a subzero treatment will lead to a greater degree of tempering. More tempering can be good or bad depending on the situation. Excessive tempering can lead to coarsening of tempering carbides which can reduce toughness. However, if the tempering was insufficient without subzero, the use of subzero processing may increase toughness due to shifting the “optimal toughness” range.
Toughness
In an earlier article where we tested the effects of heat treatment on Z-Wear toughness
Cryogenic Processing of Steel Part 1 – Maximizing Hardness
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Heat Treating and Austenitizing
During heat treatment of steel, the steel is heated to a high temperature called the “austenitizing” temperature where a phase called austenite is formed. Steel has different phases which refer to different arrangements of iron atoms within the steel. Austenite has a different set of properties from the typical room temperature phase of steel. One example of the different properties of austenite is that it is non-magnetic unlike the room temperature ferrite or martensite.
Room temperature iron/steel – Ferrite – Body Centered Cubic Atom Arrangement
High temperature iron/steel – Austenite – Face Centered Cubic Atom Arrangement
After holding the steel at the high austenitizing temperature, the steel is then rapidly quenched which transforms the steel to a phase called martensite which has high hardness. It gains its high hardness because carbon is trapped in between the atoms which makes the room temperature phase martensite as opposed to the soft ferrite.
Normal soft room temperature ferrite on the left and hard martensite on the right
All About D2 Steel – Development, Use in Knives, and Properties
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Update 10/22/2020: I now have an article with how to heat treat D2, PSF27, and CPM-D2 and it also includes toughness testing of each steel and edge retention testing of D2. https://knifesteelnerds.com/2020/08/31/how-to-heat-treat-d2-psf27-and-cpm-d2/
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D2 is a common tool steel and knife steel. It is also known by other names such as the Japanese designation SKD11, German designation 1.2379, Hitachi SLD, Uddeholm Sverker 21, and many others. How long has it been around? Where did it come from? Who started using it in knives? How do its properties compare to other steels? Find your answers here!
Early Chromium Steels
The development of D2 steel coincides in part with the invention of stainless steel as well as high speed steel. You can read
an article about the history of stainless steel here
I consider this site an excellent source for information, I learn something every time I visit.
Have a Bench Made Tagged Out Magna cut. Very tough so far
Ciao Larrin,trovo molto utile questo sito,
Avrei una domanda riguardo all’acciaio A8mod:come é meglio temprarlo per raggiungere la massima durezza?